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Pffiffiffiffiffiffiffiffiffiffiffiffiffiffi 282 Chapter 7 Covalent Bonds and Molecular Structure σ2 p π 2p 2p 2p σ2 p π 2p 2p 2p Antibonding σ2p π σ2 s Bonding Antibonding π2p σ σ2 s 2p 2p 2s 2s 2s 2s σ2 s Atomic orbitals on atom 2 Bonding σ2 s Atomic orbitals on atom 1 Atomic orbitals Molecular on atom 1 orbitals (a) N2 Molecular Atomic orbitals orbitals on atom 2 (b) O2 and F2 Albert Haim, The Relative Energies of Molecular Orbitals for Second-Row Homonuclear Diatomic Molecules; The Effect of s-p Mixing.

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