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; end e1 14 exp(-(t1tc)alpha); e2 14 exp(-(t2tr)alpha); pv(j) 14 edp þ pp((1. Consequently, the initially formed iminium ion derived from 148 can easily cyclize to give 151, whereas the isomeric iminium ion obtained from 149 must first undergo a proton loss to give the corresponding enamide 150.

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